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Accueil du site > Équipes > Arômes Parfums Synthèse Modélisation > Thème Chimie verte - chimie durable > Publications - Sylvain ANTONIOTTI

Publications - Sylvain ANTONIOTTI

64. ---- P. D. Giorgi, S. Antoniotti. Catalytic tandem reactions triggered by the introduction of a carbonyl function. Advances in Organic Synthesis, Ed. Atta-ur-Rahman, 2017. Invitation.


63. ---- B. Touati, A. El Bouakher, M. Salah Azizi, C. Taillier, R. Ben Othman, M. Trabelsi-Ayadi, S. Antoniotti, E. Duñach, V. Dalla. Atom-economical catalytic direct substitution of N,O-acetals with simple ketones.


62. ---- S. Antoniotti, J.-G. Boiteau. Réactifs nucléophiles organométalliques en synthèse organique. Théorie et applications.


61. ---- I. Notar Francesco, J.-J. Filippi, S. Antoniotti. Sustainable manufacture of a valuable fragrance ingredient : Lipase-catalysed acylation of vetiver essential oil and chemoselectivity between sesquiterpene alcohols. ChemPlusChem, 2017, 82, 3, 407-415. Link. Highlighted in the Wiley Hot topics : biocatalysis.


60. ---- H. Bouges, S. Antoniotti. Synthesis of deuterated methyleugenol via transition metal-catalysed coupling of substituted deuterated benzyl chloride with vinylmagnesium bromide. Flavour Fragr. J., 2017, 32, 3, 191-195. Link.


59. ---- P. D. Giorgi, N. Elizarov, S. Antoniotti. Selective oxidation of activated alcohols by supported gold nanoparticles under an atmospheric pressure of O2 : batch and continuous flow studies. ChemCatChem 2017, 9, 10, 1830-1836. Link. Highlighted by Wiley in Hot topics : gold.


58. ---- P. D. Giorgi, P. J. Miedziak, J. K. Edwards, G. J. Hutchings, S. Antoniotti. Bicatalytic multistep reactions en route to the one-pot total synthesis of complex molecules : easy access to chromene and 1,2-dihydroquinoline derivatives from simple substrates. ChemCatChem 2017, 9, 1, 70-75. Link. Cover picture. Highlighted by Wiley in Hot topics : sustainable chemistry.


57. ---- N. Elizarov, M. Pucheault, S. Antoniotti. Highly efficient Hosomi-Sakurai reaction of aromatic aldehydes catalyzed by Montmorillonite doped with simple bismuth(III) salts. Batch and continuous flow studies. ChemistrySelect 2016, 1, 12, 3219-3222. Link.


56. ---- S. Antoniotti. Catalyse par des nanoparticules métalliques. Techniques de l’ingénieur, 2016, AF6508.


55. ---- X. Fernandez, S. Antoniotti. Parfums : matières premières, formulations et applications. Techniques de l’ingénieur, 2016, J2304.


54. ---- L. Laurençon, T. K. T. Do, F. Hadji-Minaglou, S. Antoniotti, X. Fernandez. Fast and efficient chromatographic methods for quantification of total saponins in Solidago virgaurea L. ssp. extracts. Comparison of high pressure liquid chromatography and high performance thin-layer chromatography. J. Planar Chrom. 2016, 29, 6, 410–416.


53. ---- B. Touati, A. El Bouakher, C. Taillier, R. Ben Othman, M. Trabelsi-Ayadi, S. Antoniotti, E. Dunach, V. Dalla. Enolizable carbonyls and N,O-acetals : A rational approach for room-temperature Lewis superacid-catalyzed direct α-amidoalkylation of ketones and aldehydes. Chem. Eur. J. 2016, 22, 17, 6012–6022. Link.


52. ---- I. Notar Francesco, B. Cacciuttolo, O. Pascu, C. Aymonier, M. Pucheault, S. Antoniotti. Simple salts of abundant metals (Fe, Bi, and Ti) supported on Montmorillonite as efficient and recyclable catalysts for regioselective intramolecular and intermolecular hydroalkoxylation reactions of double bonds and tandem processes. RSC Advances, 2016, 6, 19807 - 19818. Link.


51. ---- I. Notar Francesco, B. Cacciuttolo, M. Pucheault, S. Antoniotti. Simple metal salts supported on Montmorillonite as recyclable catalysts for intramolecular hydroalkoxylation of double bonds in conventional and VOC exempt solvents. Green Chem. 2015, 17 , 2, 837 - 841. Lien.


50. ---- T. K. T. Do, F. Hadji-Minaglou, S. Antoniotti, X. Fernandez. Essential oil authenticity : a challenge for the analytical chemist. Trends Anal. Chem. 2015, 66, 146–157. Lien.


49. ---- I. Notar Francesco, J. Giauffret, F. Fontaine-Vive, J. K. Edwards, C. J. Kiely, G. J. Hutchings, S. Antoniotti. Novel radical tandem 1,6-enynes thioacylation / cyclisation : Au-Pd nanoparticles catalysis versus thermal activation as a function of the substrate specificity. Tetrahedron 2014, 70, 51, 9635–9643. Lien.


48.---- S. Antoniotti. Tuning of essential oils properties by enzymatic treatment : Towards sustainable processes for the generation of new fragrant ingredients. Molecules 2014, 19, 7, 9203-9214. (Invitation) OPEN ACCESS.


47. ---- I. Notar Francesco, F. Fontaine-Vive, S. Antoniotti. Synergies in the catalytic activity of bimetallic nanoparticles and new synthetic methods for the preparation of fine chemicals. ChemCatChem 2014, 6, 10, 2784-2791. Lien.


46. ---- K. Ben Hadj Hassen, K. Gaubert, M. Vaultier, M. Pucheault, S. Antoniotti. Comparison of homogeneous and heterogeneous Ga(III)-catalysis in the cycloisomerisation of 1,6-enynes. Green Chem. Lett. Rev. 2014, 7, 3, 243-249. OPEN ACCESS.


45. ---- T. K. T. Do, F. Hadji-Minaglou, S. Antoniotti, X. Fernandez. Secondary metabolites isolation in natural products chemistry : comparison of two semipreparative chromatographic techniques (HPLC and HPTLC). J. Chrom. A 2014, 1325, 256–260. Lien.


44. ---- P. Nava, Y. Carissan, J. Drujon, F. Grau, J. Godeau, S. Antoniotti, E. Duñach, S. Humbel. Theoretical study of the catalysis of the cycloisomerisation of 1,6-dienes with Sn(IV) salts : important role of a water molecule. ChemCatChem 2014, 6, 2, 500-507. Lien. Inside cover.


43. ---- J. Ramilijaona, E. Raynaud, C. Bouhlel, E. Sarrazin, X. Fernandez, S. Antoniotti. Enzymatic modification of palmarosa essential oil : chemical analysis and olfactory evaluation of acylated products. Chem. Biodiv. 2013, 10, 12, 2291–2301. Lien.


42. ---- J. Godeau, F. Grau, S. Antoniotti, E. Duñach. Preparation and olfactory evaluation of mono- and bicyclic compounds featuring gem-dimethylcyclohexane structures. Flavour Fragr. J. 2013, 29, 1, 59–66. Lien.


41. ---- R. Belaqziz, F. Bahri, A. Romane, S. Antoniotti, X. Fernandez, E. Duñach. Essential oil composition and antibacterial activity of the different parts of Thymus maroccanus Ball : an endemic species in Morocco(†). Nat. Prod. Res. 2013, 27, 18, 1700-1704. Lien.


40. ---- S. Antoniotti. Chimie verte - Chimie durable. Ellipses (Paris) 2013, pp 192. Lien.


39. ---- S. Antoniotti, M. Abert Vian, F. Chemat. Les huiles essentielles comme ingrédients pour une chimie « verte ». In : Fernandez, Chemat (Eds) : La chimie des huiles essentielles, 2012, Vuibert (Paris). Lien.


38. ---- J. Godeau, F. Fontaine-Vive, S. Antoniotti, E. Duñach. Experimental and theoretical studies of the bismuth triflate-catalysed cycloisomerisation reaction of 1,6,10-trienes and aryl polyenes. Chem. Eur. J. 2012, 18, 52, 16815-16822. Lien.


37. ---- V. Vece, K. Ben Hadj Hassen, S. Antoniotti, E. Duñach. C-O and C-C bonds formation in the cyclisation of gem-(dialkoxymethyl)-1,6-dienes catalysed by tin(IV) triflimidate at room temperature. Tetrahedron Lett. 2012, 53, 38, 5102-5105. Lien. Abstracted in Cheminform.


36. ---- C. Bouhlel, G.’A. Dolhem, X. Fernandez, S. Antoniotti. Model study of the enzymatic modification of natural extracts : peroxidase-based removal of eugenol from rose essential oil. J. Agric. Food Chem. 2012, 60, 4, 1052-1058. Lien.


35. ---- A.-L. Groussin, S. Antoniotti. Valuable chemicals by the enzymatic modification of molecules of natural origin : terpenoids, steroids, phenolics and related compounds. Bioresource Technol. 2012, 115, 237-243. Lien.


34. ---- O. Thomas, S. Antoniotti. Exercices et QCM de chimie organique UE1. Collection PACES, 2011, Ellipses (Paris). Lien.


33. ---- O. Thomas, S. Antoniotti. Cours de chimie organique UE1. Collection PACES, 2011, Ellipses (Paris). Lien.


32. ---- G. Genta-Jouve, S. Antoniotti, O. P. Thomas. Polyketide assembly mimics and biomimetic access to aromatic rings. In : Poupon, Nay (Eds) : Biomimetic Organic Synthesis, 2 Vol., 2011, Wiley-VCH Verlag (Weinheim). Lienvers le site de Wiley. Abstracted in Cheminform.





Highlighted in Angew. Chem. Int. Ed. 2012, 51, 583. Lien.










31. ---- J. Godeau, S. Olivero, S. Antoniotti, E. Duñach. Biomimetic cationic polyannulation reaction catalyzed by Bi(OTf)3 : cyclization of 1,6-dienes, 1,6,10-trienes and aryl trienes. Org. Lett. 2011, 13, 13, 3320-3323. Lien. Highlighted in Methods in Organic Synthesis abstracts and in Catalysts and Catalysed Reactions abstracts. Abstracted in Cheminform.


30. ---- S. Antoniotti, S. Poulain-Martini, E. Duñach. Electrophilic functionalization of non-activated olefins catalyzed by Lewis superacids. Synlett 2010, 2973-2988. Lien. Abstracted in Cheminform.


29. ---- S. Antoniotti, V. Dalla, E. Duñach. Metal Triflimidates : better than Metal Triflates as Catalysts in Organic Synthesis-the Effect of a Highly Delocalised Counter-Anion. Angew. Chem. Int. Ed. 2010, 49, 43, 860-7888. Lien. Highlighted in Catalysts and Catalysed Reactions abstracts and in Methods in Organic Synthesis abstracts. Abstracted in Cheminform.


28. ---- R.-M. Dia, R. Belaqziz, A. Romane, S. Antoniotti, E. Duñach. Flavouring and odorant thiols from renewable resources by InIII-catalysed hydrothioacetylation and lipase-catalysed solvolysis. Tetrahedron Lett. 2010, 51, 16, 2164-2167. Lien. Abstracted in Cheminform.


27. ---- R. Ben Othman, R. Affani, M.-J. Tranchant, S. Antoniotti, V. Dalla, E. Duñach. N-Acyliminium ions chemistry : highly efficient and versatile carbon-carbon bond formation by nucleophilic substitution of hydroxyl groups catalyzed by Sn(NTf2)4. Angew. Chem. Int. Ed. 2010, 49, 776-780. HOT PAPER. Lien. Highlighted in Catalysts and Catalysed Reactions abstracts and in Methods in Organic Synthesis abstracts. Abstracted in Cheminform. .


26. -----S. Antoniotti, E. Duñach. Tin(IV) triflimidate-catalyzed cyclization of epoxy esters to functionalized δ-hydroxy-γ-lactones. Tetrahedron Lett. 2009, 50, 21, 2536-2539. Lien. Highlighted in Methods in Organic Synthesis abstracts. Abstracted in Cheminform.


25. -----S. Antoniotti. 4th French-Italian Chemistry Congress : Environment and Sustainable Development. C. R. Chim. 2009, 12, 8, 829-830. Lien.


24. -----J. Godeau, S. Olivero, S. Antoniotti, E. Duñach. Lewis superacids derived from triflic and triflimidic acids and their use as catalysts in 1,6-dienes cycloisomerisation. C. R. Chim. 2009, 12, 8, 911-915 . Lien.


23. -----X. Fernandez, S. Antoniotti, E. Bussotti, M.-P. Hurel. Parfum, chimie et création. Actual. Chim. 2008, 323-324, 42-51. Lien.


22. -----P. Y. Toullec, E. Genin, S. Antoniotti, J.-P. Genêt, V. Michelet. Au2O3 as a highly stable and efficient catalyst for the selective cycloisomerisation of -acetylenic carboxylic acids to -alkylidene -butyrolactones. Synlett 2008, 707-711. Lien. Highlighted in the Organic Chemistry Portal, in Catalysts and Catalysed Reactions abstracts and in Methods in Organic Synthesis abstracts. Abstracted in Cheminform.


21. -----S. Antoniotti, X. Fernandez, E. Duñach. Substrate scope evaluation of hydrolases and enzymatic reaction design. Biocatal. Biotransfor. 2008, 26, 3, 228-234. Lien.


20. -----S. Antoniotti, E. Duñach. Facile preparation of metallic triflates and triflimidates by oxidative dissolution of metal powders. Chem. Comm. 2008, 993-995. Lien.


19. -----P. Lemechko, F. Grau, S. Antoniotti, E. Duñach. Hydroalkoxylation of non-activated olefins catalysed by Lewis superacids in alcoholic solvents : An eco-friendly reaction. Tetrahedron Lett. 2007, 48, 5731-5734. Lien. Abstracted in Cheminform.

L’introduction de cet article a été plagiée dans un article paru 2 ans plus tard. Plagiarism of the introduction of his article occured 2 years after in : Tetrahedron Letters, 2009, 50, 5783-5785. Lien.


18. -----F. Berrué, S. Antoniotti, O. Thomas, P. Amade. Bioinspired metal-catalysed Doebner - Knoevenagel condensations between malonic acid half thioesters and aldehydes. Eur. J. Org. Chem. 2007, 11, 1743-1748 . Lien. Highlighted in Catalysts and Catalysed Reactions abstracts. Abstracted in Cheminform.


17. -----E. Genin, P. Y. Toullec, P. Marie, S. Antoniotti, C. Brancour, J.-P. Genêt, V. Michelet. Gold catalysis in organic synthesis : efficient intramolecular cyclization of gamma-acetylenic carboxylic acids to 5-exo-alkylidene-butyrolactones. ARKIVOC 2007, V, 67-78. Lien.


16. -----R. F. Klees, P. C. De Marco, R. M. Salasznyk, D. Ahuja, M. G. Hogg, S. Antoniotti, L. Kamath, J. S. Dordick, G. E. Plopper. Apocynin derivatives interrupt intracellular signalling resulting in decreased migration in breast cancer cell. J. Biomed. Biotechnol. 2006, 1-10. Lien.


15. -----S. Antoniotti, J. Golebiowski, D. Cabrol-Bass, E. Duñach. Density Functional Theory investigations on acid-catalysed epoxide oxidative ring-opening by DMSO. Competition between oxidation processes. J. Mol. Struct. (Theochem) 2006, 763, 155-9. Lien.


14. ------E. Genin, P. Y. Toullec, S. Antoniotti, C. Brancour, J.-P. Genêt, V. Michelet. Room Temperature Au(I)-Catalyzed exo-Selective Cycloisomerization of Acetylenic Acids : An Entry to Functionalized -Lactones. J. Am. Chem. Soc. 2006, 128, 3112-3113. Lien. Highlighted in the Organic Chemistry Portal. Abstracted in Cheminform.

*** Ranked in the JACS most-cited articles in 2006 ***

as of December 31, 2006 (#13)

as of December 31, 2007 (#20)


13. ------E. Genin, S. Antoniotti, V. Michelet, J.-P. Genêt. An Ir(I)-catalyzed exo-selective tandem cycloisomerization / hydroalkoxylation of bis-homopropargylic alcohols at room temperature. Angew. Chem. Int. Ed. 2005, 44, 4949-53. Lien. Highlighted in Catalysts and Catalysed Reactions abstracts. Abstracted in Cheminform.


12. ------S. Antoniotti, E. Genin, V. Michelet, J.-P. Genêt. Highly efficient access to strained bicyclic ketals via gold-catalyzed cycloisomerization of bis-homopropargylic diols. J. Am. Chem. Soc. 2005, 127, 9976-9977. Lien. Highlighted in Methods in Organic Synthesis abstracts. Abstracted in Cheminform.


11. ------S. Antoniotti, J. S. Dordick. Peroxidase-catalyzed coupling of solid-supported ortho-methoxyphenols. Adv. Synth. Catal. 2005, 347, 1119-24. Lien.


10. ------S. Antoniotti, S. Antonczak, J. Golebiowski. Acid-catalysed oxidative ring-opening of epoxide by DMSO. Theoretical investigation of the effect of acid catalysts and substituents. Theor. Chem. Acc. 2004, 112, 290-7. Lien.


9. ------S. Antoniotti, E. Duñach. Mechanistic aspects of the Bi-catalysed oxidation of epoxides to -diketones. Eur. J. Org. Chem. 2004, 3459-64. Lien. Highlighted in Catalysts and Catalysed Reactions abstracts.


8. ------S. Antoniotti, E. Duñach. Utilisations récentes de dérivés du bismuth en synthèse organique. Comptes Rendus Chimie 2004, 7, 679-88. Lien. Abstracted in Cheminform.


7. ------S. Antoniotti, N. Alezra, X. Fernandez, E. Duñach. Catalytic epoxide oxidation : a novel access to various flavouring and odorant -diketones. Flavour Frag. J. 2004, 19, 373-81. Lien. Highlighted in Methods in Organic Synthesis abstracts.


6. ------S. Antoniotti, L. Santhanam, D. Ahuja, M. G. Hogg, J. S. Dordick. Structural diversity of peroxidase-catalyzed oxidation products of ortho-methoxyphenols. Org. Lett. 2004, 6, 1975-8. Lien.


5. ------S. Antoniotti, E. Duñach. Studies on the catalytic oxidation of epoxides to alpha-diketones by Bi(0)/O2 in DMSO. J. Mol. Catal. A 2004, 208, 135-45. Lien.


4. ------S. Antoniotti, E. Duñach. Epoxide oxidations : a valuable tool in organic synthesis. Synthesis 2003, 2753-62. Lien. Highlighted in Methods in Organic Synthesis abstracts. Abstracted in Cheminform.


3. ------S. Antoniotti. Bismuth(III) trifluoromethanesulfonate. Synlett 2003, 1566-7. Lien.

*** Ranked in the 5 most cited Synlett spotlights over 10 years (see here). ***


2. ------S. Antoniotti, E. Duñach. Direct and catalytic synthesis of quinoxaline derivatives from epoxides and ene-1,2-diamines. Tetrahedron Lett. 2002, 43, 3971-3. Lien. Highlighted in Methods in Organic Synthesis abstracts. Abstracted in Cheminform.


1. ------S. Antoniotti, E. Duñach. Novel and catalytic oxidation of internal epoxides to -diketones. Chem. Commun. 2001, 2566-7. Lien. Abstracted in Cheminform.



Brevets d’invention : 3. BIOTECHNOLOGICAL MANUFACTURE OF VETIVERYL ESTERS. I. NOTAR FRANCESCO, J. RAMILIJAONA, J.-J. FILIPPI, S. ANTONIOTTI (Université Nice Sophia Antipolis/CNRS, FR), WO2016193208 (A1) - 2015-05-29. Lien espacenet.


2. PREPARATION OF METAL SALTS OF TRIFLIC ACID AND OF TRIFLIMIDIC ACID UNDER ULTRASOUND TREATMENT. J. R. Desmurs ; E. Duñach ; S. Olivero ; S. Antoniotti (Université de Nice - Sophia Antipolis/CNRS/CDP-Innovation, FR), WO2012010752 (A1) ― 2012-01-26. Lien espacenet.


1. METHOD FOR TRANSFORMING A 1,2-DISUBSTITUTED EPOXIDE CYCLE INTO ITS ALPHA-DIKETONE DERIVATIVE. E. Duñach ; S. Antoniotti (Rhodia Chimie, FR), Fr 2829490, PCT WO 03/022789 A2, 2003. Lien espacenet.