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Accueil du site > Équipes > Arômes Parfums Synthèse Modélisation > Thème Synthèse et méthodologies catalytiques > Gilles LEMIERE

Gilles LEMIERE

- CNRS Researcher (CR2)
- APSM Team
- Member of the “Synthèse et Méthodologies Catalytiques” group

+33(0)4 92 07 61 31

Mail : gilles.lemiere@unice.fr

Research Interests

  • Homogeneous Catalysis (Pd, Pt, Au, Bi...)
  • Cycloisomerisation Reactions
  • Asymmetric Synthesis
  • Total Synthesis

Academic Career

Publications

  • Cycloisomerization of Allene–Enol Ethers under Bi(OTf)3 Catalysis Ondet, P. ; Joffrin, A. ; Diaf, I. ; Lemiere, G. ; Dunach, E. Org. Lett. 2015, 17, 1002-1005. link

  • Bi(III)-catalysed synthesis of substituted indanes by a double hydroarylation of unactivated 1,3-dienes Cacciuttolo, B. ; Ondet, P. ; Poulain-Martini, S. ; Lemiere, G. ; Dunach, E. Org. Chem. Frontiers 2014, 1, 765-769. link

  • Poly(vinyl alcohol) Functionalization with Aldehydes in Organic Solvents : Shining Properties of Poly(vinyl acetals) Delattre, E. ; Lemière, G. ; Boulay, B. ; Desmurs, J.R. ; Dunach, E. J. Appl. Polym. Sci. 2014, 131, 40677. link

  • Metal Triflate-Catalysed Synthesis of Polycyclic Tertiary Alcohols by Cyclisation of gamma-Allenic Ketones Diaf, I. ; Lemière, G. ; Dunach, E. Angew. Chem., Int. Ed. 2014, 53, 4177-4180. link

  • Catalytic Activation of Olefins by Metal Triflates and Triflimides : Application to Fragrance Chemistry. Lemière, G. ; Dunach, E. Chem. Eur. J. 2013, 19, 3270-3280. link

  • Bi(OTf)3- Catalyzed Cycloisomerization of Aryl-Allenes. Lemière, G. ; Cacciuttolo, B. ; Belhassen, E. ; Duñach, E. Org. Lett. 2012, 14, 2750-2753 link

Postdoctoral

  • Geometry-selective synthesis of the unsaturated side chains of the isodomoic acids Fleary-Roberts, N. ; Lemière G. ; Clayden, J.* Tetrahedron, 2015, sous presse (Alan R. Katrizky memorial issue)
  • Dearomatizing Reactions Using Organolithiums. (book chapter) Lemière, G. ; Clayden, J. Science of Synthesis, Knowledge Updates 2011, 4, 139-190
  • A General Synthetic Approach to the Amnesic Shellfish Toxins : Total Synthesis of (−)-Isodomoic Acid B, (−)-Isodomoic Acid E and (−)-Isodomoic Acid F. Lemière, G. ; Sedehizadeh, S. ; Toueg, J. ; Fleary-Roberts N. ; Clayden J. Chem. Commun. 2011, 47, 3745-3547 link

Postgraduate

  • Ring Expansions Within Gold-Catalyzed Cycloisomerization of O-tethered 1,6-enynes. Application to the Synthesis of Natural Product-like Macrocycles. Simonneau, A. ; Harrak, Y. ; Jeanne-Julien, L. ; Lemière, G. ; Mouriès-Mansuy, V. ; Goddard, J-P. ; Malacria, M. ;Fensterbank, L. ChemcatChem 2013, 1096-1099 link
  • Gold(I)-Catalyzed Cyclization of beta-Allenylhydrazones : An efficient Synthesis of Multisubstituted N-Aminopyrroles. Benedetti, E. ; Lemière, G. ; Chapellet, L.-L. ; Penoni, A. ; Palmisano, G. ; Malacria, M. ; Goddard, J.-P. ; Fensterbank, L. Org. Lett. 2010, 12, 4396-4399 link
  • Generation and Trapping of Cyclopentenylidene Gold Species : Four Pathways to Polycyclic Compounds. Lemière, G. ; Gandon, V. ; Cariou, K. ; Hours, A. ; Fukuyama, T. ; Dhimane A.-L. ; Fensterbank, L. ; Malacria, M. J. Am. Chem. Soc. 2009, 131, 2993-3006 link
  • Gold- and Platinum-Catalyzed Cycloisomerization of Enynyl Esters versus Allenyl Esters : An Experimental and Theorical Study. Marion, N. ; Lemière, G. ; Correa, A. ; Costabile, C. ; Ramón, R. S. ; Moreau, X. ; de Frémont, P. ; Dahmane, R. ; Hours, A. ; Lesage, D. ; Tabet, J.-C. ; Goddard, J.-P. ; Gandon, V. ; Cavallo, L. ; Fensterbank, L. ; Malacria, M. ; Nolan, S. P. Chem. Eur. J. 2009, 15, 3243-3260 link
  • The role of Bent Acyclic Allene Gold Complexes in Axis-to-Center Chirality Transfers. Gandon, V. ; Lemière, G. ; Hours, A. ; Fensterbank, L. ; Malacria, M. Angew. Chem., Int. Ed. 2008, 47, 7534-7538 link
  • Gold- Vs Platinum-Catalyzed Polycyclizations by O-Acyl Migration.Solvent free reactions. Moreau, X. ; Goddard, J.-P. ; Bernard, M. ; Lemière, G. ; López-Romero, J.M. ; Mainetti, E. ; Marion, N. ; Mouriès, V. ; Thorimbert, S. ; Fensterbank, L. ; Malacria, M. Adv. Synth. Catal. 2008, 43-48 link
  • Tandem Gold(I) Catalyzed Cyclization/Electrophilic Cyclopropanation of Vinyl Allenes. Lemière, G. ; Gandon, V. ; Cariou, K. ; Fukuyama, T. ; Dhimane, A.-L. ; Fensterbank, L. ; Malacria, M. Org. Lett. 2007, 9, 2207-2209 link
  • Gold(I)- and Gold(III)- Catalyzed Cycloisomerization of Allenynes : A Remarkable Halide Effect. Lemière, G. ; Gandon, V. ; Agenet, N. ; Goddard, J.-P. ; de Kozak, A. ; Aubert, C. ; Fensterbank, L. ; Malacria, M. Angew. Chem., Int. Ed. 2006, 45, 7596-7599 link
  • PtCl2 and PtCl4 Catalyzed Cycloisomerization of Polyunsaturated Precursors. Marco-Contelles, J. ; Arroyo, N. ; Shazia, A. ; Mainetti, E. ; Marion, N. ; Cariou, K. ; Lemière, G. ; Mouriès, V. ; Fensterbank, L. ; Malacria, M. Eur. J. Org. Chem. 2006, 4618-4633 link
  • Au(I) Catalyzed Cycloisomerization of 1,5-Enynes bearing a propargylic acetate : formation of unexpected bicyclo[3,1,0]hexene. Marion, N. ; de Frémont, P. ; Lemière, G. ; Stevens, E. D. ; Fensterbank, L. ; Malacria, M. ; Nolan, S. P. Chem. Commun. 2006, 2048-2050 link

Undergraduate

  • Lanthanide Complexes of monovacant Dawson Polyoxotungstate [α1-P2W17O61]10- as selective and Recoverable Catalyst for Lewis-Acid Promoted Organic Transformations. Boglio, C. ; Lemière, G. ; Hasenknopf, B. ; Thorimbert, S. ; Lacôte, E. ; Malacria, M. Angew. Chem., Int. Ed. 2006, 45, 3324-3327 link