Partenaires



Rechercher

Sur ce site

Sur le Web du CNRS


Accueil du site > Équipes > Matériaux et Polymères Eco-Compatibles (MAPEC) > Polymères thermodurcissables

Polymères thermodurcissables

Publications/brevets

2017
A. Codou, N. Guigo, J. G. van Berkel, E. Jong, N. Sbirrazzuoli.
Preparation and crystallization behavior of Poly(ethylene 2,5-furandicarboxylate)/cellulose composites by twin screw extrusion.
Carbohydrates Polymers, 2017, 174, 1026–1033.

T. Liavitskaya, N. Guigo, N. Sbirrazzuoli, S. Vyazovkin.
Further insights into the kinetics of thermal decomposition during continuous cooling.
Phys Chem Chem Phys, 2017, 19(29), 18836-18844.

N. Bosq, N. Guigo, D. Aht-Ong, N. Sbirrazzuoli.
Crystallization of Poly(butylene succinate) on Rapid Cooling and Heating : Towards Enhanced Nucleation by Graphene Nanosheets.
J. Phys. Chem. C, 2017, 121 (21), 11915-11925.

N. Bosq, N. Guigo, G. Falco, J. Persello, N. Sbirrazzuoli,
Impact of silica nanoclusters on furfuryl alcohol polymerization and molecular mobility.
J. Phys. Chem. C, 2017, 121(13), 7485-7494.

N. Guigo, J. van Berkel, E. de Jong, N. Sbirrazzuoli.
Modelling the non-isothermal crystallization of polymers : application to poly(ethylene 2,5-furandicarboxylate).
Thermochim. Acta, 2017, 650, 66-75.

J.M. Pin, A. Mija, N. Sbirrazzuoli.
Stereodynamic control of star-epoxy/anhydride crosslinking actuated by liquid-crystalline phase Transitions (Back-cover).
Soft Matter, 2017, 13, 1956-1965.

L. Martino, N. Guigo, J. G. van Berkel, N. Sbirrazzuoli.
Influence of organically modified montmorillonite and sepiolite clays on the physical properties of bio-based Poly(ethylene 2,5-furandicarboxylate).
Composites Part B, 2017, 110, 96-105.

2016
L. Martino, V. Niknam, N. Guigo, J. G. van Berkel, N. Sbirrazzuoli.
Morphology and thermal properties of novel clay-based Poly (ethylene 2,5-furandicarboxylate) (PEF) nanocomposites.
RSC Advances, 2016, 6, 59800-59807.

D. G. Papageorgiou, N. Guigo, V. Tsanaktsis, S. Exarhopoulos, D. N. Bikiaris, N. Sbirrazzuoli, G. Z. Papageorgiou.
Fast Crystallization and Melting Behavior of a Long-Spaced Aliphatic Furandicarboxylate Biobased Polyester, Poly(dodecylene 2,5-furanoate)
Industrial & Engineering Chemistry Research, 2016, 55(18), 5315-5326.


A. Codou, M. Moncel, J. G. van Berkel, N. Guigo, N. Sbirrazzuoli.
Glass Transition Dynamics and Cooperativity Length of Poly(ethylene 2,5-furandicarboxylate) compared to Poly(ethylene terephthalate).
Phys. Chem. Chem. Phys., 2016, 18, 16647 – 16658. (Back cover)

J-M Pin, N. Sbirrazzuoli, L. Sacarascu, A. Mija.
Star-epoxy mesogen with 1,3,5-triazine core : a model of A4B3 fractal polymerization in a liquid-crystalline thermoset media.
Polymer Chemistry, 2016, 7(6), 1221-1225.

L. Martino, N. Guigo, J. G. van Berkel, J. J. Kolstad, N. Sbirrazzuoli.
Nucleation and Self-Nucleation of Bio-based Poly(ethylene 2,5-furandicarboxylate) Probed by Fast Scanning Calorimetry.
Macromolecular Materials and Engineering, 2016, 301(5), 586-596.

2015
J. M. Pin, N. Guigo, L. Vincent, N. Sbirrazzuoli, A. Mija.
Copolymerization as a Strategy to Combine Epoxidized Linseed Oil and Furfuryl Alcohol : The Design of a Fully Bio-Based Thermoset. (Inside cover)
ChemSusChem, 2015, 8, 4149 – 4161.

V. Tsanaktsis, D. N. Bikiaris, N. Guigo, S. Exarhopoulos, D. G. Papageorgiou, N. Sbirrazzuoli, G. Z. Papageorgiou.
Synthesis, properties and thermal behavior of Poly(decylene 2,5-furanoate) : a biobased polyester from 2,5-furan dicarboxylic acid.
RSC Advances, 2015, 5, 74592-74604.

A. Codou, N. Guigo, L. Heux, N. Sbirrazzuoli.
Partial periodate oxidation and thermal cross-linking for the processing of thermoset All-Cellulose composites.
Composites Science and Technology, 2015, 117, 54-61.

S. Barale, L. Vincent, G. Sauder, N. Sbirrazzuoli.
Deconvolution of calorimeter response from electrical signals forextracting kinetic data.
Thermochim. Acta, 2015, 615, 30–37.

N. Bosq, N. Guigo, L. Vincent, N. Sbirrazzuoli.
Thermomechanical Behavior of a Novel Biobased Poly(Furfurylalcohol) / Silica Nanocomposite Elaborated by Smart Functionalization of Silica Nanoparticles.
Polym. Degrad. Stab., 2015, 118, 137-146.

G. Z. Papageorgiou, N. Guigo, V. Tsanaktsis, D. G. Papageorgiou, S. Exarhopoulos, N. Sbirrazzuoli, D. N. Bikiaris.
On the bio-based furanic polyesters : Synthesis and thermal behavior study of poly(octylene furanoate) using fast and temperature modulated scanning calorimetry.
European Polymer Journal, 2015, 68, 115–127.

J. M. Pin, N. Sbirrazzuoli, A. Mija. From epoxidized linseed oil to bio-resin : an overall approach of epoxy/anhydride cross-linking.
ChemSusChem, 2015, 8(7), 1232-1243.

J. G. van Berkel, N. Guigo, J. J. Kolstad, L. Sipos, B. Wang, M. A. Dam, N. Sbirrazzuoli.
Isothermal crystallization kinetics of Poly (ethylene 2,5-furandicarboxylate).
Macromolecular Materials and Engineering, 2015, 300(4), 466-474.

J. Alves Marins, A. Mija, J-M. Pin, F. Giulieri, B. Soares, N. Sbirrazzuoli, P. Lançon, G. Bossis.
Anisotropic Reinforcement of Epoxy-Based Nanocomposites with Aligned Magnetite-Sepiolite Hybrid Nanofiller.
Composites Science and Technology, 2015, 112, 34-41.

2014
A. Codou, N. Guigo, J. van Berkel, E. de Jong, N. Sbirrazzuoli.
Nonisothermal Crystallization Kinetics of biobased Poly(ethylene 2,5-furandicarboxylate) synthesized via direct esterification process. (Cover-featured article).
Macromol. Chem. Phys., 2014, 215, 2065−2074.

N. Guigo, K. Mazeau, J. L. Putaux, L. Heux.
Surface modification of cellulose microfibrils by periodate oxidation and subsequent reductive amination with benzylamine : a topochemical study.
Cellulose, 2014, 21(6), 4119-4133.

J.M. Pin, N. Guigo, A. Mija, L. Vincent, N. Sbirrazzuoli, J. C. van der Waal, E. de Jong.
Valorization of Biorefinery Side-Stream Products : Combination of Humins with Polyfurfuryl Alcohol for Composite Elaboration.
ACS Sustainable Chem. Eng., 2014, 2, 2182-2190.

S. Vyazovkin, K. Chrissafis, M. L. Di Lorenzo, N. Koga, M. Pijolat, B. Roduit, N. Sbirrazzuoli, J. Josep Suñol.
ICTAC Kinetics Committee Recommendations for Collecting Thermal Analysis Data for Kinetic Computations.
Thermochim. Acta, 2014, 590, 1-23. Highly cited paper (Web of Science).

N. Bosq, N. Guigo, J. Persello, N. Sbirrazzuoli.
Melt and glass crystallization of PDMS and PDMS silica nanocomposites.
Phys. Chem. Chem. Phys., 2014, 16 (17), 7830 - 7840.

2013
S. Kadi, S. Djadoun, N. Sbirrazzuoli.
Thermal stability and kinetic study of poly (ethyl methacrylate-co-acrylonitrile) nanocomposites prepared by in situ polymerization in presence of an Algerian bentonite.
Thermochim. Acta, 2013, 569, 127-133.

N. Sbirrazzuoli.
Determination of pre-exponential factors and of the mathematical functions f(alpha) or G(alpha) that describe the reaction mechanism in a model-free way.
Thermochim. Acta, 2013, 564, 59-69.

N. Bosq, N. Guigo, E. Zhuravlev, N. Sbirrazzuoli.
Non-isothermal crystallization of polytetrafluoroethylene in wide range of cooling rates.
J. Phys. Chem. B, 2013, 117, 3407-3415.

K. Ouaad, S. Djadoun, L. Vincent, N. Sbirrazzuoli.
Elaboration and Thermal behavior of Nanocomposites based on Poly(Ethyl methacrylate) and Thermal behavior of Nanocomposites based on Poly(Ethyl methacrylate) and an Algerian Bentonite prepared via in situ polymerization initiated by Ni(II)α-Benzoinoxime Complex.
Thermochim. Acta, 2013, 555, 30-36.

2012
R. Zavaglia, N. Guigo, N. Sbirrazzuoli, A. Mija, L. Vincent.
Complex Kinetic Pathway of Furfuryl Alcohol Polymerization Catalyzed by Green Montmorillonite Clays.
J. Phys. Chem. B, 2012, 116 (28), 8259–8268.

N. Guigo, N. Sbirrazzuoli, S. Vyazovkin.
Atypical gelation in gelatin solutions probed by ultra-fast calorimetry. (Cover-featured article).
Soft Matter, 2012, 8(27), 7116–7121.

C. Alzina, A. Mija, L. Vincent, N. Sbirrazzuoli.
Effects of Incorporation of Organically Modified Montmorillonite on the Reaction Mechanism of Epoxy/Amine Cure.
J. Phys. Chem. B, 2012, 116, 5786−5794.

N. Guigo, N. Sbirrazzuoli, S. Vyazovkin.
Gelation on heating of supercooled gelatin solutions.
Macromol. Rapid Commun., 2012, 33(8), 698-702.

2011
C. Alzina, N. Sbirrazzuoli, A. Mija.
Epoxy-amine based nanocomposites reinforced by silica nanoparticles. Relationships between morphologic aspects, cure kinetics and thermal properties.
J. Phys. Chem. C, 2011, 115(46), 22789-22795.

Y. Gaillard, A. Mija, A. Burr, E. Darque-Ceretti, E. Felder, N. Sbirrazzuoli.
Green material blends from renewable resources. Polymorphic transitions and phase diagram of beeswax/rosin resin.
Thermochim. Acta, 2011, 521, 1-2, 90-97.

S. Vyazovkin, A. K. Burnham, J. M. Criado, L. A. Pérez-Maqueda, C. Popescu, N. Sbirrazzuoli.
ICTAC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data.
Thermochim. Acta, 2011, 520, 1-19. The most cited article in TCA since 2009. Highly cited paper (Web of Science).

S. Ovarlez, F. Giulieri, F. Delamare, N. Sbirrazzuoli, A.-M. Chaze.
Indigo-sepiolite nanohybrids : Temperature-dependent synthesis of two complexes and comparison with indigo-palygorskite systems.
Microporous and Mesoporous Materials, 2011, 142(1), 371-380.

K. Ouaad, S. Djadoun, H. Ferfera-Harrar, N. Sbirrazzuoli, L. Vincent.
Synthesis and Thermal Behaviour of Poly(methyl methacrylate)/Maghnia Bentonite Nanocomposite prepared at room temperature via in situ polymerization initiated by a new Ni(II)α-Benzoinoxime Complex.
J. Applied Polym. Sci., 2011, 119(6), 3227-3233.

2010
C. Alzina, N. Sbirrazzuoli, A. Mija.
Hybrid Nanocomposites : Advanced Nonlinear Method for Calculating Key Kinetic Parameters of Complex Cure Kinetics.
J. Phys. Chem. B, 2010, 114, 12480-12487.

N. Guigo, A. Mija, L. Vincent, N. Sbirrazzuoli.
Eco-friendly composite resins based on renewable biomass resources. Polyfurfuryl alcohol/lignin thermosets.
Eur. Polym. J., 2010, 46(5), 1016-1023.

2009
N. Guigo, L. Vincent, A. Mija, H. Näegele, N. Sbirrazzuoli.
Innovative green nanocomposites based on silicate clays/lignin/natural fibres.
Composite Science and Technology, 2009, 69, 1979–1984.

N. Guigo, A. Mija, R. Zavaglia, L. Vincent, N. Sbirrazzuoli.
New insights on the thermal degradation pathways of neat polyfurfuryl alcohol and polyfurfuryl alcohol/SiO2 hybrid materials.
Polym. Degrad. Stab., 2009, 94, 908-913.

N. Sbirrazzuoli, L. Vincent, A. Mija, N. Guigo.
Integral, differential and advanced isoconversional methods. Complex mechanisms and isothermal predicted conversion-time curves.
Chemom. Intell. Lab. Syst., 2009, 96, 219-226.

N. Guigo, A. Mija, L. Vincent, N. Sbirrazzuoli.
Molecular mobility and relaxation process of isolated lignin studied by multifrequency calorimetric experiments.
Phys. Chem. Chem. Phys., 2009, 11, 1227-1236.

K. ElMiloudi, S. Djadoun, N. Sbirrazzuoli, S. Géribaldi.
Miscibility, phase behaviour of binary and ternary homoblends of poly(styrene-co-acrylic acid), poly(styrene-co-N,N-dimethylacrylamide) and poly(styrene-co-4-vinylpyridine).
Thermochim. Acta, 2009, 483, 49-54

2007
S. Vyazovkin, L. Vincent, N. Sbirrazzuoli.
Thermal denaturation of collagen analyzed by isoconversional method (Cover-featured article).
Macromol. Biosci., 2007, 7, 1181–1186.

L. Vincent, A. Mija, N. Sbirrazzuoli.
Liquid crystalline and isotropic epoxy thermosets. Mechanism and kinetics of thermal degradation
Polym. Degrad. Stab., 2007, 92(11), 2051-2057.

N. Guigo, A. Mija, L. Vincent, N. Sbirrazzuoli.
Chemorheological analysis and model-free kinetics of acid catalysed furfuryl alcohol polymerization
Phys. Chem. Chem. Phys., 2007, 9(39), 5359-5366.

N. Sbirrazzuoli.
Is the Friedman Method Applicable to Transformations with Temperature Dependent Reaction Heat ?
Macromol. Chem. Phys., 2007, 208, 1592-1597.

2006
S. Vyazovkin, N. Sbirrazzuoli.
Isoconversional kinetic analysis of thermally stimulated processes in polymers (Cover-featured article).
Macromol. Rapid Commun., 2006, 27, 1515-1532.

N. Sbirrazzuoli, A. Mititelu-Mija, L. Vincent, C. Alzina.
Isoconversional kinetic analysis of stoichiometric and off-stoichiometric epoxy-amine cures
Thermochim. Acta, 2006, 447, 167-177.

S. Vyazovkin, N. Sbirrazzuoli, I. Dranca.
Variation in activation energy of the glass transition for polymers of different dynamic fragility.
Macromol. Chem. Phys., 2006, 207, 1126-1130.

2005
K. Elmiloudi, M. Benygzer, S. Djadoun, N. Sbirrazzuoli, S. Géribaldi.
FT-IR spectroscopy and hydrogen bonding interactions in poly(styrene-co-methacrylic acid) / poly(styrene-co-4-vinylpyridine) blends.
Macromol. Symp., 2005, 230(1), 39-50.

S. Vyazovkin, J. Stone, N. Sbirrazzuoli.
Hoffman-Lauritzen parameters for nonisothermal crystallization of poly(ethylene terephthalate) and poly(ethylene oxide) melts.
J. Therm. Anal. Calorim., 2005, 80, 177-180.

N. Sbirrazzuoli, S. Vecchio, A. Catalani.
Isoconversional kinetic study of alachlor and metolachlor vaporization by thermal analysis.
Int. J. Chem. Kinet., 2005, 37(2), 74-80.

H. Nogent, X. Le Tacon, L. Vincent, N. Sbirrazzuoli.
DRC signal treatment for heat flow and reagents accumulation determination.
J. Loss Prevent. Proc., 2005, 18(1), 43-48.

2004
S. Vyazovkin, N. Sbirrazzuoli, I. Dranca.
Variation of the effective activation energy throughout the glass transition.
Macromol. Rapid Commun., 2004, 25(19), 1708-1713.

F. Dimier, N. Sbirrazzuoli, B. Vergnes, M. Vincent.
Curing kinetics and chemorheological analysis of polyurethane formation.
Polym. Eng. Sci., 2004, 44(3) 518-527.

S. Vyazovkin, N. Sbirrazzuoli.
Isoconversional approach to evaluating the Hoffman-Lauritzen parameters (U* and Kg) from the overall rates of nonisothermal melt crystallization.
Macromol. Rapid Commun., 2004, 25(6), 733-738.

2003
S. Vyazovkin, A. Mititelu, N. Sbirrazzuoli.
Kinetics of epoxy-amine curing accompanied by the formation of liquid crystalline structure.
Macromol. Rapid Commun., 2003, 24(18), 1060-1065.

N. Sbirrazzuoli, S. Vyazovkin, A. Mititelu, C. Sladic, L. Vincent.
A study of epoxy-amine cure kinetics by combining isoconversional analysis with temperature modulated DSC and dynamic rheometry.
Macromol. Chem. Phys., 2003, 204(15), 1815-1821.

S. Vyazovkin, N. Sbirrazzuoli.
Estimating the activation energy for nonisothermal crystallization of polymer melts.
J. Therm. Anal. Calorim., 2003, 72(2), 681-686.

S. Vyazovkin, N. Sbirrazzuoli.
Isoconversional analysis of calorimetric data on nonisothermal crystallization of a polymer melt.
J. Phys. Chem. B, 2003, 107(3), 882-888.

C. Cordella, J. P. Faucon, D. Cabrol-Bass, N. Sbirrazzuoli.
Application of differential scanning calorimetry as a tool for honey floral species characterization and adulteration detection.
J. Therm. Anal. Calorim., 2003, 71(1), 279-290.

2002
S. Vyazovkin, N. Sbirrazzuoli.
Isoconversional analysis of the nonisothermal crystallization of a polymer melt.
Macromol. Rapid Commun., 2002, 23(13), 766-770.

L. Vincent, N. Sbirrazzuoli, S. Vyazovkin.
Evaluation of the dynamic response of a new heat flux calorimeter for kinetic purposes.
Ind. Eng. Chem. Res., 2002, 41(26), 6650-6655.

C. Cordella, I. Moussa, A. C. Martel, N. Sbirrazzuoli, L. Lizzani-Cuvelier.
Recent developments in food characterization and adulteration detection : techniques oriented perspectives (review).
J. Agric. Food Chem., 2002, 50(7), 1751-1764.

N. Sbirrazzuoli, S. Vyazovkin.
Learning about epoxy cure mechanisms from isoconversional analysis of DSC data.
Thermochim. Acta, 2002, 388(1-2), 289-298 (invited paper).

C. Cordella, J. F. Antinelli, C. Aurieres, J. P. Faucon, D. Cabrol-Bass, N. Sbirrazzuoli.
Use of Differential Scanning Calorimetry (DSC) as a new technique for detection of adulteration in honeys : 1- Study of adulteration effect on honey thermal behavior.
J. Agric. Food Chem., 2002, 50(1), 203-208.

2001
J. Gaucheron, C. Boulanger, C. Santaella, N. Sbirrazzuoli, P. Vierling.
In vitro cationic lipid-mediated gene delivery with fluorinated glycerophosphoethanolamine helper lipids.
Bioconjugate Chem., 2001, 12(6), 949-963.

2000
N. Sbirrazzuoli, L. Vincent, S. Vyazovkin.
Comparison of several computational procedures for evaluating the kinetics of thermally stimulated condensed phase reactions.
Chemom. Intell. Lab. Syst., 2000, 54(1), 53-60.

N. Sbirrazzuoli, L. Vincent, S. Vyazovkin.
Electronic solution to the problem of a kinetic standard for DSC measurements.
Chemom. Intell. Lab. Syst., 2000, 52(1), 23-32.

S. Vyazovkin, N. Sbirrazzuoli.
Kinetic analysis of isothermal cures performed below the limiting glass transition temperature.
Macromol. Rapid Commun., 2000, 21(2), 85-90.

S. Vyazovkin, N. Sbirrazzuoli.
Effect of viscosity on the kinetics of initial cure stages.
Macromol. Chem. Phys., 2000, 201(2), 199-203.

S. Vyazovkin, N. Sbirrazzuoli.
Kinetic methods to study isothermal and nonisothermal epoxy-anhydride cure.
Macromol. Chem. Phys., 1999, 200(10), 2294-2303.

S. Vyazovkin, N. Sbirrazzuoli.
Isoconversional method to explore the mechanism and kinetics of multi-step epoxy cures.
Macromol. Rapid Commun., 1999, 20(7), 387-389.

N. Sbirrazzuoli, L. Vincent, J. Bouillard, L. Élégant.
Isothermal and nonisothermal kinetics : when mechanistic information available.
J. Therm. Anal. Calorim., 1999, 56(2), 783-792.

S. Vyazovkin, N. Sbirrazzuoli.
Confidence intervals for the activation energy estimated by a few experiments.
Anal. Chim. Acta, 1997, 355(2-3), 175-180.

N. Sbirrazzuoli, D. Brunel, L. Élégant.
Neural networks for kinetic parameters determination, signal filtering and deconvolution in thermal analysis (invited paper).
J. Therm. Anal. Calorim., 1997, 49(3), 1553-1564.

N. Sbirrazzuoli, Y. Girault, L. Élégant.
Simulations for evaluation of kinetic methods in differential scanning calorimetry. Part 3 - Peak maximum evolution methods and isoconversional methods.
Thermochim. Acta, 1997, 293(1-2), 25-37.

N. Sbirrazzuoli, D. Brunel.
Computational neural networks for mapping calorimetric data : application of feed-forward neural networks to kinetic parameters determination and signal filtering.
Neural Comput. & Applic., 1997, 5, 20-32.

S. Vyazovkin, N. Sbirrazzuoli.
Mechanism and kinetics of epoxy-amine cure studied by differential scanning calorimetry.
Macromolecules, 1996, 29 (6), 1867-1873.

N. Sbirrazzuoli.
Simulations for evaluation of kinetic methods in differential scanning calorimetry. Part 2 - Effect of additional noise on single peak methods.
Thermochim. Acta, 1996, 273, 169-184.

Chapitres de livre

N. Guigo, N. Sbirrazzuoli.
Thermal Analysis of biobased polymers and composites, in Handbook of Thermal Analysis and Calorimetry, volume 5 : Recent Advances, Techniques and Applications, second Edition, edited by Sergey Vyazovkin, Nobuyoshi Koga and Christoph Schick, Elsevier, 2018.

N. Sbirrazzuoli, N. Guigo, S. Vyazovkin.
Isoconversional Kinetics by Fast Scanning Calorimetry, in Fast Scanning Calorimetry, Vincent Mathot & Christoph Schick, Editors, Springer International Publishing AG, 2016.

Brevets

E. de Jong, J. C. van der Waal, J.M. Pin, N. Guigo.
Composition comprising furfuryl alcohol. WO 2015088341, 2015.

A. Mija, E. de Jong, J.C. van der Waal, G. van Klink
Humins containing foam, WO 2017/074183, PCT/NL2016/050742

A. Mija, E.de Jong, J.C. Van der Waal, G. Klink
Process for the modification of humins : P32901NL00/RLA.